Metamerism 101:
When brown is green and red is blue
By Jeff Lewis, Laboratory Manager
Have
you ever awakened in the morning and, in the warm glow of your tungsten-lit
bedroom, put on a pair of brown socks – then when you reach the
cold, fluorescent light of the office, you realize that you are actually
wearing one brown and one green sock?
You have just become the victim of metamerism and if you are a colorist
by profession, it is worth a trip back home to change. While
it is an embarrassing situation, in certain commercial applications
it can be costly as well.
Metamerism (also called paramerism, but for practical purposes, we
will stick to the more common and accepted meta prefix), can
be defined as occurring when a pair of objects appear to match under
one set of conditions and fail to match under alternate conditions.
There are three types of metamerism: illuminant, observer and geometric.
Observer and geometric metamerism are rarely encountered in industry,
so we will focus on illuminant metamerism in this article.
It must be understood that color is a perception (sensation), not
an intrinsic quality of an object. Without going into a full
color course, the color we perceive is the result of light interacting
with and being modified by an object. This modified light is
then reflected or transmitted to an observer who then interprets the
results. This interpretation is what we call color.
The object’s contribution to the color is restricted to its
absorption of specific wavelengths of light. The ‘color’ we
perceive is what remains—the reflected light. Since what’s
left is the combination of the light and the object, we are only subjected
to the combined stimuli.
Metamerism occurs when two objects, which have different spectral
absorption distributions, are made to match in a specific illuminant,
such as daylight. These objects, when viewed under tungsten light,
could appear very different in apparent color. The reason for
this is that tungsten has a much stronger red component than daylight. Discrepancies
in the absorption in this area of the spectrum will be enhanced. The
result is a visual mismatch.
The simplest method of eliminating metamerism is to strive for a curve
match—where both the visual color and the spectral curve of the
objects match. Depending on circumstances, this is not always
possible. For example, if the standard panel is an ink swatch
or a thermoplastic chip, the colorants used to make that standard may
not be appropriate for the intended application.
Factors, such as light or temperature resistance or toxicity restrictions,
may dictate selection of a pigment that is not used in the standard.
In these cases, it is necessary to choose a primary illuminant to do
the match, and then to measure and be aware of the color differences
that will be encountered in alternate illumination conditions. The
colorant supplier and customer must work closely to avoid confusion and
disappointment in the color matching process.
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